(2,2′-Bipyridine-κ2 N,N′)bis(N-ethyl-N-phenyldithiocarbamato-κ2 S,S′)cadmium(II) chloroform solvate
نویسندگان
چکیده
In the title compound, [Cd(C(9)H(10)NS(2))(2)(C(10)H(8)N(2))]·CHCl(3), the Cd(II) atom exists in an all-cis distorted octa-hedral geometry. Chelation is isobidentate for one dithio-carbamate ligand and anisobidentate for the other. The chloroform solvent mol-ecule is disordered over two positions of equal occupancy.
منابع مشابه
(2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2 S,S′]cadmium(II) acetonitrile solvate
The title complex, [Cd(C(6)H(12)NOS(2))(2)(C(10)H(8)N(2))]·CH(3)CN, features a distorted octa-hedral N(2)S(4) geometry for the Cd(II) centre defined by a pair of asymmetrically chelating dithio-carbamate ligands as well as a 2,2'-bipyridine ligand. Supra-molecular chains along [001] are formed in the crystal structure, mediated by O-H⋯S hydrogen bonds; the acetonitrile solvent mol-ecules are as...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009